The difference between PA6 and PA66 is small.
Why choose PA6?
- Good bearing properties; low friction, low wear. PA6 is known as “bearing material”.
- Good fatigue resistance
- Good impact resistance, even at low temperatures
- Excellent chemical resistance, especially against fuel and oil
- Good thermal resistance, better than POM
- Better dimensional accuracy than POM
- Better surface quality than POM
Why not choose?
- PA6 absorbs moisture which might decrease its strength and tensile modulus by half.
- The surface of the components feels slightly oily. This, in some cases, might not give the desired quality appearance.
- Small technical parts in printers
- Screw anchors
- Stadium seats
Why choose PA66 over PA6?
- Slightly better short term thermal resistance
- Absorbs slightly less moisture
- Higher modulus
- Better wear resistance
- Better short term heat resistance
Why not choose?
- Higher price than PA6 (not dramatically, might be worth the money)
- For visual parts, PA6 has slightly better surface quality and processability
- Cable ties
- Ski bindings
The differences are small, however, and in some circumstances, some of the items on the list above may be invalid, depending on the exact grade in use.
Some practical experiences of unfilled PA6/PA66:
- Water absorption is a well-known property of PA and worth taking into account. The difference can be felt when a product that has been stored outdoors over winter is taken indoors for a few days: its stiffness invariably increases.
- High-quality cable ties are made of PA66. This illustrates well the strength and toughness of the material. It also reveals that unfilled PA is suitable for applications that require high flexibility or even an integral hinge. Apart from cable ties, products made of unfilled PA66 are not very common. PA6 appears to be a much more popular choice.
- Because of its good surface appearance, PA6 is also often used (rather than amorphous plastics ABS, PC, PC/ABS) on the housings of some outdoor applications, for example, a lawnmower and a chainsaw
- Even though parts made of PA can have a glossy surface, replacing amorphous grades like ABS with PA might cause problems because of the higher shrinkage and therefore warpage.
Note: Both PA6 and PA66 require proper drying before processing.